Application of Poly(3,4-ethylenedioxythiophene):Polystyrenesulfonate/Polypyrrole Counter Electrode for Dye-Sensitized Solar Cells

被引：95
|
作者：
Yue, Gentian [1 ]
Wu, Jihuai [1 ]
Xiao, Yaoming [1 ]
Lin, Jianming [1 ]
Huang, Miaoliang [1 ]
Lan, Zhang [1 ]
机构：
[1] Huaqiao Univ, Engn Res Ctr Environm Friendly Funct Mat, Minist Educ, Inst Mat Phys Chem, Quanzhou 362021, Peoples R China
来源：
JOURNAL OF PHYSICAL CHEMISTRY C | 2012年 / 116卷 / 34期
基金：
中国国家自然科学基金; 国家高技术研究发展计划(863计划);
关键词：
LOW-COST; POLYPYRROLE NANOPARTICLES; THIN-FILMS; PERFORMANCE; EFFICIENCY; GRAPHENE;
D O I：
10.1021/jp303958r
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A low-cost poly(3,4-ethylenedioxythiophene):polystyrenesulfonate (PEDOT:PSS) and polypyrrole (PPy) composite film was fabricated on a regid fluorine-doped tin oxide (FTO) substrate used as the counter electrode in a dye-sensitized solar cell (DSSC) by a facile electrochemical polymerization method. The cyclic voltammetry and electrochemical impedance spectroscopy measurements show that the PEDOT:PSS/PPy film has a low surface resistance, high conductivity, and good catalytic performance for the I-/I-3-electrolyte. The power conversion efficiency of the DSSC based on the PEDOT:PSS/PPy counter electrode reaches 7.60% under a simulated solar light illumination of 100 mW.cm(-2); the efficiency is comparable to that of the DSSCs based on a sputtered Pt electrode.
引用
收藏
页码：18057 / 18063
页数：7
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