1,8-Diazabicyclo[5.4.0]undec-7-ene-Catalyzed Carbonylative Cyclization of Propargylic Alcohols with Elemental Sulfur

被引：11
|
作者：
Hu, Yuya [1 ]
Yin, Zhiping [1 ]
Werner, Thomas [1 ]
Spannenberg, Anke [1 ]
Wu, Xiao-Feng [1 ,2 ]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany
[2] Zhejiang Sci Tech Univ, Dept Chem, Xiasha Campus, Hangzhou 310018, Zhejiang, Peoples R China
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 2018卷 / 10期
关键词：
Carbonylation; Cyclization; Sulfur; Heterocycles; Alkynes; CARBON-MONOXIDE; CATALYZED CARBONYLATION; ASSISTED CARBONYLATION; PRACTICAL SYNTHESIS; BOND FORMATION; AMINES; DERIVATIVES; 1,3-OXATHIOLAN-2-ONES; HETEROCYCLES; EPOXIDES;
D O I：
10.1002/ejoc.201701813
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A carbonylation procedure involving the cyclization of propargylic alcohols with elemental sulfur was developed. With 1,8-diazabicyclo[5.4.0]undec-7-ene as the catalyst, elemental sulfur and carbon monoxide are activated and incorporated into propargylic alcohols. Good to excellent yields of the desired sulfur-containing heterocycles were obtained at room temperature.
引用
收藏
页码：1274 / 1276
页数：3
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