One-pot In-situ Synthesis of Sn/Carbon-fibers Nanocomposite by Chemical Vapor Deposition and Its Li-storage Properties

被引:8
|
作者
Xie, J. [1 ]
Zheng, Yunxiao [1 ]
Liu, Shuangyu [1 ]
Cao, Gaoshao [1 ]
Zhao, Xinbing [1 ]
机构
[1] Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310027, Zhejiang, Peoples R China
关键词
Sn/carbon-fibers; In-situ catalytic growth; Three-dimensional conductive network; Li-storage properties; LITHIUM-ION BATTERIES; NEGATIVE ELECTRODE MATERIALS; ANODE MATERIALS; ELECTROCHEMICAL PERFORMANCE; DE-LITHIATION; NANOPARTICLES; ALLOYS; COMPOSITES; NANOTUBE;
D O I
10.1016/S1005-0302(12)60053-X
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Sn/carbon-fibers (CFs) nanocomposite has been prepared by chemical vapor deposition with in-situ catalytic growth of CFs. The nanocomposite has been characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM) and Raman spectrum. The electrochemical performance of the nanocomposite has been investigated by galvanostatic cycling and cyclic voltammetry (CV). It has been found that a three-dimensional conductive network forms by the interconnected CFs, which offers conductive channels for the Sn nanoparticles. The nanocomposite gives a first charge capacity of 385 mAh.g(-1) and exhibits an improved cycling stability than bare Sn.
引用
收藏
页码:275 / 279
页数:5
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