Dynamics of water molecules in micropores of AIPO4-5 and SAPO-5 studied by 1H NMR

被引:0
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作者
Gotoh, K [1 ]
Ishimaru, S [1 ]
Ikeda, R [1 ]
机构
[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan
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O6 [化学];
学科分类号
0703 ;
摘要
Dynamics of water molecules in one-dimensional micropores AlPO4-5 and SAPO-5 frameworks was studied by measuring H-1 NMR spectra, second moment M-2 of line-width and spin-lattice relaxation time T-1. Although the presence of two kinds of water molecules free and bound on the capillary wall were reported in AlPO4-5, our NMR T-1 results imply the absence of two kinds of H2O motions, but the motional rate distributes from slow to fast jumps in both AlPO4-5 and SAPO-5.
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页码:1250 / 1251
页数:2
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