Supramolecular frameworks based on [60]fullerene hexakisadducts

被引：4
|
作者：
Kraft, Andreas [1 ,2 ]
Stangl, Johannes [3 ]
Krause, Ana-Maria [1 ,2 ]
Mueller-Buschbaum, Klaus [3 ]
Beuerle, Florian [1 ,2 ]
机构：
[1] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany
[2] Univ Wurzburg, Ctr Nanosyst Chem, D-97074 Wurzburg, Germany
[3] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
来源：
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 13卷
关键词：
fullerenes; hexakisadducts; hydrogen bonding; porous materials; structure elucidation; BONDED ORGANIC FRAMEWORK; CAGE COMPOUNDS; EXCEPTIONAL STABILITY; BUILDING-BLOCKS; CO2; ADSORPTION; GAS-STORAGE; LUMINESCENCE; SEPARATION; SORPTION; FULLERENES;
D O I：
10.3762/bjoc.13.1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[60]Fullerene hexakisadducts possessing 12 carboxylic acid side chains form crystalline hydrogen-bonding frameworks in the solid state. Depending on the length of the linker between the reactive sites and the malonate units, the distance of the [60]fullerene nodes and thereby the spacing of the frameworks can be controlled and for the most elongated derivative, continuous channels are obtained within the structure. Stability, structural integrity and porosity of the material were investigated by powder X-ray diffraction, thermogravimetry and sorption measurements.
引用
收藏
页码：1 / 9
页数：9
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