Magnetic Properties of NiIICrIII Layered Double Hydroxide Materials

被引：34
|
作者：
Almansa, Juan J. [1 ]
Coronado, Eugenio [1 ]
Marti-Gastaldo, Carlos [1 ]
Ribera, Antonio [1 ]
机构：
[1] Univ Valencia, Inst Ciencia Mol, Valencia 46980, Spain
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 36期
关键词：
Layered compounds; Chromium; Nickel; Magnetic properties; Spin frustration;
D O I：
10.1002/ejic.200800658
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This paper describes the isolation of four layered double hydroxide (LDH) compounds having the general formula [(Ni3-xCrxIII)-Cr-II(OH)(6)](CO3)(x/2)center dot yH(2)O [x = 0.57 (1), 0.69 (2), 0.81 (3) and 0.93 (4)] by using homogeneous precipitation methods and varying the metal ratio in the synthetic solutions. All the reported compounds have carbonate anions in the interlamellar space. This fact forces the interlayer distances to remain unchanged in all the cases, thus providing an ideal system in which the changes observed in magnetic properties can be correlated with metal composition along the hydroxide layers. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
引用
收藏
页码：5642 / 5648
页数：7
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