SYNTHESIS OF SUNDIVERSIFOLIDE AND DIVERSIFOLIDE VIA A DIASTEREOSELECTIVE [3+2] NITRILE OXIDE CYCLOADDITION REACTION

被引：8

作者：

Sasaki, Hiroyuki ^{[1
]}

Yokoe, Hiromasa ^{[1
]}

Shindo, Mitsuru ^{[2
]}

Yoshida, Masahiro ^{[1
]}

Shishido, Kozo ^{[1
]}

机构：

[1] Univ Tokushima, Grad Sch Pharmaceut Sci, Tokushima 7708505, Japan

[2] Kyushu Univ, Inst Mat Chem & Engn, Kasuga, Fukuoka 8168580, Japan

来源：

HETEROCYCLES | 2009年 / 77卷 / 02期

基金：

日本学术振兴会;

关键词：

Sesquiterpene; Diastereoselective Synthesis; 1,3-Dipolar Cycloaddition; Allelopathy; Kinetic Protonation; (+)-SUNDIVERSIFOLIDE; REDUCTION; SUBSTANCE;

D O I：

10.3987/COM-08-S(F)67

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The enantioselective synthesis of the unnatural enantiomers (-)-sundiversifolide and (+)-diversifolide has been accomplished employing a diastereoselective intramolecular [3+2] nitrile oxide cycloaddition reaction as the key step.

引用

页码：773 / 777

页数：5

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