Hydrophosphinylation of unactivated alkenes with secondary phosphine oxides under visible-light photocatalysis

被引：106
|
作者：
Yoo, Woo-Jin [1 ]
Kobayashi, Shu [1 ]
机构：
[1] Univ Tokyo, Dept Chem, Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan
来源：
GREEN CHEMISTRY | 2013年 / 15卷 / 07期
基金：
日本科学技术振兴机构; 日本学术振兴会;
关键词：
PHOSPHORUS-CENTERED RADICALS; CARBON BOND FORMATION; PHOTOREDOX CATALYSIS; P BOND; C-C; CHEMISTRY; FUNCTIONALIZATION; DERIVATIVES; REACTIVITY; ADDITIONS;
D O I：
10.1039/c3gc40482j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A visible light induced hydrophosphinylation of unactivated alkenes with diaryl phosphine oxides was found to occur with good yields and under mild reaction conditions in the presence of an inexpensive and commercially available organic dye as a photocatalyst.
引用
收藏
页码：1844 / 1848
页数：5
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