Friedel-Crafts reaction of toluene with oxalyl chloride

被引:0
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作者
Sakaino, Y
Sugawara, K
Terao, Y
Fujiwara, T
Mori, Y
Maeda, K
机构
[1] SHIMANE UNIV,FAC SCI,DEPT INFORMAT SCI,MATSUE,SHIMANE 690,JAPAN
[2] OCHANOMIZU UNIV,FAC SCI,DEPT CHEM,BUNKYO KU,TOKYO 112,JAPAN
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中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
By the Friedel-Crafts reaction of toluene with oxalyl chloride, three kinds of fluorene derivatives (c, d, e), naphthalene derivative f, fluorenone derivative g, were obtained in addition to 4,4'-dimethyl benzophenone b.. In the compounds (c, d, e, f, g), c shows thermochromism above 135 degrees C in solution, while e emits phosphorescence and f exhibits fluorescence at room temperature in the solid states.
引用
收藏
页码:A271 / A275
页数:5
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