Synthesis and Insecticidal Activities of Novel Sulfur(oxygen) Containing Oxime Ethers as well as Structure Activity Relationship

被引：0

作者：

Liu, Ai-Ping ^{[1
,2
]}

Wang, Xiao-Guang ^{[1
]}

Ou, Xiao-Ming ^{[1
]}

Liu, Shu-Dong ^{[1
]}

Mo, Hong-Bo ^{[1
,3
]}

Liu, Xin-Ping ^{[1
]}

Wang, Ting-Jin ^{[1
,2
]}

He, Hai-Jun ^{[1
,3
]}

Hu, Li ^{[1
]}

Huang, Ming-Zhi ^{[1
]}

Liu, Zhao-Jie ^{[2
]}

Yao, Jian-Ren ^{[2
,4
]}

机构：

[1] Hunan Res Inst Chem Ind, Natl Engn Res Ctr Agrochem, Changsha 410007, Hunan, Peoples R China

[2] Cent China Normal Univ, Inst Organ Synth, Wuhan 430079, Peoples R China

[3] Hunan Normal Univ, Coll Chem & Chem Engn, Changsha 410081, Hunan, Peoples R China

[4] Chinese Acad Agr Sci, Inst Plant Protect, Beijing 100094, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 28卷 / 10期

关键词：

sulfur(oxygen) containing oxime ether; insecticidal activity; homoptera; lepidoptera;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

96 novel sulfur(oxygen) containing 1-aryl O-benzyl oximes were synthesized by the reaction of sulfur(oxygen) containing 1-aryl oximes with the corresponding halides of pyrethriod alcohols in the presence of sodium hydroxide and phase transfer catalyst or with triethylquaternary ammonium salts of halides of pyrethriod alcohol in the presence of sodium hydroxide. The title compounds were identified by MS, H-1 NMR, IR spectra and elemental analyses. Bioassay showed that these compounds showed remarkable insecticidal activities against homopteran and lepidopteran pests. C-74 and C-93 showed a medial effective dose [LC50/(mg.L-1)] of 1.4, 0.63 and 0.31, 1.2 against oriental army worm and leafhopper respectively, the LC50 values of compounds C-74 and C-93 were better than that of the commercialized insecticide fenvalerate.

引用

页码：1772 / 1779

页数：8

共 12 条

[1] ALKYL ARYL KETONE OXIME O-ETHERS - A NOVEL GROUP OF PYRETHROIDS
BULL, MJ
DAVIES, JH
SEARLE, RJG
HENRY, AC
[J]. PESTICIDE SCIENCE, 1980, 11 (02): : 249 - 256
[2] FUJIMOTO K, 1975, Patent No. 236555
[3] HIRANO M, Patent No. 2737297
[4] Synthesis and insecticidal activities of novel oxime ether pyrethroids
Liu, AP
Ou, XM
Huang, MZ
Wang, XG
Liu, XP
Wang, YJ
Chen, C
Yao, JR
[J]. PEST MANAGEMENT SCIENCE, 2005, 61 (02) : 166 - 170
[5] LIU AP, 2005, Patent No. 1687019
[6] LIU AP, 2004, Patent No. 1546462
[7] LIU AP, 2000, Patent No. 1250046
[8] LIU AP, 2000, Patent No. 1125931
[9] LIU AP, 2001, Patent No. 1288002
[10] [刘曙东 Liu Shudong], 2002, [化学试剂, Chemical Reagents], V24, P41

← 1 2 →