Spiropyrans and spirooxazines 9. Photochromism of novel cationic spirooxazines

被引：1
|
作者：
Metelitsa, A. V. [1 ]
Voloshin, N. A. [2 ]
Besuglyi, S. O. [2 ]
Solov'eva, E. V. [1 ]
Shepelenko, K. E. [1 ]
Abubikerova, Yu R. [1 ]
Minkin, V. I. [1 ,2 ]
机构：
[1] Southern Fed Univ, Inst Phys & Organ Chem, Rostov Na Donu 344090, Russia
[2] Russian Acad Sci, Southern Sci Ctr, Rostov Na Donu 344006, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2013年 / 62卷 / 02期
基金：
俄罗斯基础研究基金会;
关键词：
nitrosonaphthol; nitrosoquinolinol; spirocyclic compounds; spirooxazines; spirooxazinoquinolines; spirooxazine salts; merocyanines; photochromism; colorability; molecular switches; MAGNETIC-PROPERTIES; SINGLE-CRYSTALS; ISOMERIZATION; MEROCYANINE; SOLVATOCHROMISM; MOLECULES; FRAGMENT; DYES;
D O I：
10.1007/s11172-013-0073-6
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Novel photochromic spirooxazinoquinolines, their cationic derivatives, and cationic spirooxazine containing pyridinium cation in the aliphatic side chain of the oxazine moiety of the molecule were synthesized. Quaternization of the quinoline fragment leads to a substantial increase in the thermal stability of the merocyanine isomers of cationic spirooxazines and a decrease in the efficiency of photocoloration. Pyridinium cation in the aliphatic side chain of the spirooxazine does not exert a substantial effect on the kinetics of photocoloration and thermal bleaching.
引用
收藏
页码：529 / 535
页数：7
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