From dinuclear, chain to sheet: Synthesis, structural characterization and luminescence properties of silver(I) complexes based on rigid and flexible pyridyl-containing ligands

被引：23
|
作者：
Huang, Xu [1 ]
Li, Zhong-Feng [1 ]
Jin, Qiong-Hua [1 ]
Qiu, Qi-Ming [1 ]
Cui, Yang-Zhe [1 ]
Yang, Qin-Rui [1 ]
机构：
[1] Capital Normal Univ, Dept Chem, Beijing 100048, Peoples R China
来源：
POLYHEDRON | 2013年 / 65卷
基金：
中国国家自然科学基金;
关键词：
Silver(I) complexes; Triphenylphosphine; 4,4 '-Bipyridine; 1,3-Bis(4-pyridyl)propane; 1,2-Di(4-pyridyl)ethane; Terahertz time-domain methods; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; PHOTOLUMINESCENT PROPERTIES; SERIES; 1D;
D O I：
10.1016/j.poly.2013.08.018
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of triphenylphosphine (PPh3) and 4,4'-bipyridine (bipy), 1,2-di(4-pyridyl)ethane (dpa), 1,3-bis(4-pyridyl)propane (bpp) ligands with AgX (X = BF4 and NO2) lead to five new complexes: {[Ag(PPh3)(2)(bpp)](BF4)}(n) (1), [Ag(dpa)(BF4)](n) n (2), {[Ag(PPh3)(2)(mu-bipy)](2)(BF4)(2)}(n) (3) and {[Ag(PPh3)(2)(CH3-CN)](2)(mu-bipy)}(BF4)(2) (4) and [Ag(dpa)(NO2)In (5). In 1, 2 and 3, the Ag atoms are bridged by pyridyl-containing ligands (bpp, dpa and bipy, respectively) to form infinite chain structure. In 4, the Ag atoms are bridged by bipyridine to form a dinuclear structure. Complex 5 is of layer structure which is formed by silver atoms, oxygen atoms from NO2- and dpa. All the complexes are characterized by X-ray diffraction, fluorescence and H-1 NMR spectroscopy. (C) 2013 Elsevier Ltd. All rights reserved.
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收藏
页码：129 / 135
页数：7
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