Study on comparison of reducing ability of three organic hydride compounds

被引:31
|
作者
Feng, Yi-Si [2 ]
Yang, Chun-Yan [2 ]
Huang, Qiang [1 ]
Xu, Hua-Jian [1 ]
机构
[1] Hefei Univ Technol, Sch Mech Engn, Hefei 230009, Peoples R China
[2] Hefei Univ Technol, Sch Chem Engn, Hefei 230009, Peoples R China
基金
中国国家自然科学基金;
关键词
Organic hydride compounds; Reducing ability; Irradiation; ASYMMETRIC TRANSFER HYDROGENATION; ORGANOCATALYTIC TRANSFER HYDROGENATION; ALPHA; BETA-UNSATURATED CARBONYL-COMPOUNDS; ENANTIOSELECTIVE TRANSFER HYDROGENATION; CATALYZED TRANSFER HYDROGENATION; ELECTRON-TRANSFER REACTIONS; ALPHA-IMINO ESTERS; CONJUGATE REDUCTION; BETA-EPOXY KETONES; THYMIDYLATE SYNTHASE;
D O I
10.1016/j.tet.2012.04.047
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Selective reduction of three kinds of substrates were studied to evaluate the reducing abilities of N,N-dimethyl-benzimidazolidine (DMBI), 2-phenylbenzimidazoline (PBI) and 2-phenylbenzothiazoline (PBT). As hydride donors, these three five-membered heterocyclic compounds performed different reducing abilities depending on the substrates. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5053 / 5059
页数:7
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