Syntheses, characterization and properties of manganese, cobalt and copper complexes from chelate N-donor ligands

被引：7
|
作者：
Kuai, Hai-Wei [1 ]
Xia, Jing-Jing [2 ]
Sang, Hai-Yun [2 ]
机构：
[1] Huaiyin Inst Technol, Fac Chem Engn, Huaian 223003, Peoples R China
[2] Huaiyin Inst Technol, Key Lab Traff & Transportat Secur Jiangsu Prov, Huaian 223003, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2016年 / 72卷
关键词：
Dinuclear complex; Oxazoline; Non-linear optics; Ferroelectricity; Magnetism; METAL; TEMPERATURE; FRAMEWORKS; SILVER;
D O I：
10.1016/j.inoche.2016.08.011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
2-[(S)-4-isopropyl-2-oxazolyl]quinoline (L-1) and 2-[(S)-4-phenyl-2-oxazolyl]quinoline (L-2) react with manganese, cobalt and copper salts to yield four new complexes: [Mn-2(L-1)(2)[Cl-2 (1), {[C0(L-1)(2)](2)(OH)}(C10(4))(3) (2), [Cu2I2(L-1)(2)] (3), and {[Cu(L-2)(2)](2)(OH)}(BF4)(3)center dot H2O (4), which were fully characterized by single-crystal and powder X-ray diffraction, IR, elemental and thermogravimetric analyses. Complexes 1-4 all show dinuclear structure. Two metal ions are bridged by Cl- in 1, by OH- in 2 and 4, and by I- in 3, Moreover, non-linear optical, and ferroelectric and magnetic properties have been investigated. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：73 / 77
页数：5
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