Chemoselective reduction of halo-nitro aromatic compounds by β-cyclodextrin-modified transition metal catalysts in a biphasic system

被引：0
|
作者：
Reetz, MT [1 ]
Frömbgen, C [1 ]
机构：
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
来源：
SYNTHESIS-STUTTGART | 1999年 / 09期
关键词：
beta-cyclodextrin modified diphosphine; phase transfer catalysis; catalytic reduction; supramolecular catalysis; transition metals;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Transition metal complexes of a water-soluble beta-cyclodextrin modified diphosphine can be used in the biphasic (H2O/organic) hydrogenation of halo-nitro aromatic compounds. The platinum complex is the most active and selective, resulting in the chemoselective formation of halo-aniline derivatives.
引用
收藏
页码：1555 / 1557
页数：3
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