Mechanism of Selective Oxidations of Hydrocarbons with Hydrogen Peroxide Catalyzed by Metalloporphyrins

被引：0
|
作者：
Li Fengying [1 ]
Liu Ye [1 ]
Wang Xia [1 ]
He Xiaoshuang [1 ]
Ding Xia [1 ]
机构：
[1] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
来源：
PROGRESS IN CHEMISTRY | 2008年 / 20卷 / 11期
关键词：
iron porphyrins; manganese porphyrins; selective oxidation; mechanism; hydrogen peroxide;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Recent researches on mechanism of hydrocarbon selective oxidations with hydrogen peroxide catalyzed by metalloporphyrins including iron porphyrins and manganese porphyrins are reviewed in this paper. The strategies to promote heterolytic cleavage of hydrogen peroxide to facilitate the formation of active high valent metal-oxo species are discussed in detail.
引用
收藏
页码：1635 / 1641
页数：7
相关论文
共 56 条
  • [1] ANELLI PL, 1989, CHEM COMMUN, P779
  • [2] ANELLI PL, 1993, PURE APPL CHEM, P1345
  • [3] [Anonymous], 1994, METALLOPORPHYRINS CA
  • [4] Epoxidation and hydroxylation reactions catalysed by beta-tetrahalogeno and beta-octahalogeno manganese porphyrins.
    Baciocchi, E
    Boschi, T
    Cassioli, L
    Galli, C
    Lapi, A
    Tagliatesta, P
    [J]. TETRAHEDRON LETTERS, 1997, 38 (41) : 7283 - 7286
  • [5] Banfi S., 1991, CHEM COMMUN, P1285
  • [6] MONOOXYGENASE-LIKE OXIDATION OF HYDROCARBONS BY H2O2 CATALYZED BY MANGANESE PORPHYRINS AND IMIDAZOLE - SELECTION OF THE BEST CATALYTIC-SYSTEM AND NATURE OF THE ACTIVE OXYGEN SPECIES
    BATTIONI, P
    RENAUD, JP
    BARTOLI, JF
    REINAARTILES, M
    FORT, M
    MANSUY, D
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (25) : 8462 - 8470
  • [7] BATTIONI P, 1986, CHEM COMMUN, P341
  • [8] Campestrini S, 2001, ADV SYNTH CATAL, V343, P819, DOI 10.1002/1615-4169(20011231)343:8<819::AID-ADSC819>3.0.CO
  • [9] 2-Y
  • [10] CAO XZ, 2007, INORG CHEM, P593
123456