Crystal structure of Cs2[UO2(SeO4)2•H2O]•H2O

被引：0

作者：

Mikhailov, YN

Gorbunova, YE

Shishkina, OV

Serezhkina, LB

Serezhkin, VN

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

[2] Samara State Univ, Samara 443011, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2001年 / 46卷 / 11期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single crystals of Cs-2[UO2(Seo(4))(2) (.) H2O] (.) H2O (I), synthesized by the isothermal solubility method at 25 degreesC, were studied by X-ray crystallography. Crystals are orthorhombic, a = 14.367 Angstrom, b = 11.682 Angstrom, c = 7.826 Angstrom, Z = 4, space group Pna2(1). Compound I is a representative of crystal-chemical group A (B2M1)-M-2 (A UO22+) of uranyl complexes and is characterized by a layered structure of uranium-containing groups [UO2(SeO4)(2) (.) H2O](2-); cesium ions and water molecules are located between the layers.

引用

页码：1661 / 1665

页数：5

共 50 条

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