ZnO clusters: Laser ablation production and time-of-flight mass spectroscopic study

被引:41
|
作者
Dmytruk, A. [1 ,4 ]
Dmitruk, I. [2 ,4 ]
Blonskyy, I. [1 ]
Belosludov, R. [3 ]
Kawazoe, Y. [3 ]
Kasuya, A. [4 ]
机构
[1] Natl Acad Sci Ukraine, Inst Phys, UA-03028 Kiev, Ukraine
[2] Natl Taras Shevchenko Univ Kyiv, Dept Phys, UA-03122 Kiev, Ukraine
[3] Tohoku Univ, Inst Mat Res, Sendai, Miyagi 9808577, Japan
[4] Tohoku Univ, Interdisciplinary Res Ctr, Sendai, Miyagi 9808578, Japan
关键词
Zinc oxide; Cluster; Magic number; Time-of-flight mass spectroscopy; SPECTROMETRY;
D O I
10.1016/j.mejo.2008.07.010
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Zinc oxide clusters have been produced by laser ablation of bulk powder zinc peroxide in vacuum and investigated by time-of-flight mass spectroscopy. Experimental results revealed unpredicted and hitherto unknown (ZnO), clusters of enhanced stability ("magic clusters") at n = 34, 60 and 78. Cage-like structures for the magic clusters have been suggested, supported by first-principles calculations. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:218 / 220
页数:3
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