Greening the Wacker process

被引：33
|
作者：
Kulkarni, Mukund G. [1 ]
Shaikh, Yunnus B. [1 ]
Borhade, Ajit S. [1 ]
Chavhan, Sanjay W. [1 ]
Dhondge, Attrimuni P. [1 ]
Gaikwad, Dnyaneshwar D. [1 ]
Desai, Mayur P. [1 ]
Birhade, Deekshaputra R. [1 ]
Dhatrak, Nagorao R. [1 ]
机构：
[1] Univ Pune, Dept Chem, Pune 411007, Maharashtra, India
来源：
TETRAHEDRON LETTERS | 2013年 / 54卷 / 19期
关键词：
Wacker oxidation; Palladium; Potassium bromate; Terminal olefin; PALLADIUM-CATALYZED OXIDATION; PROTECTED ALLYLIC AMINES; TERMINAL OLEFINS; METHYL KETONES; SELECTIVE OXIDATION; AEROBIC OXIDATION; MOLECULAR-OXYGEN; BENZYLIDENE ACETALS; EFFICIENT CATALYST; INTERNAL OLEFINS;
D O I：
10.1016/j.tetlet.2013.01.082
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Wacker oxidation of various terminal olefins with Pd-0/C-KBrO3, a nontoxic, environmentally benign, and easy to handle catalyst system, was achieved in high isolated yields. The described protocol offers an alternative to the traditional Wacker system which uses CuCl2 as co-catalyst. The catalyst is reusable while maintaining high activity and selectivity. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2293 / 2295
页数：3
相关论文
共 50 条
12345