Gas-Phase Maleic Anhydride Hydrogenation Over Ni/SiO2-Al2O3 Catalysts: Effect of Metal Loading

被引：18
|
作者：
Meyer, C. I. [1 ]
Regenhardt, S. A. [1 ]
Bertone, M. E. [1 ]
Marchi, A. J. [1 ]
Garetto, T. F. [1 ]
机构：
[1] Univ Nacl Litoral CONICET, Catalysis Sci & Engn Res Grp GICIC, Inst Invest Catalisis & Petroquim INCAPE, Santa Fe, Argentina
来源：
CATALYSIS LETTERS | 2013年 / 143卷 / 10期
关键词：
Ni-based catalysts; Hydrogenolysis; gamma-Butyrolactone; Maleic anhydride; NH3; decomposition; GAMMA-BUTYROLACTONE; NICKEL-CATALYSTS; AMMONIA DECOMPOSITION; NI(110) SURFACE; TETRAHYDROFURAN; ADSORPTION; CONVERSION; ACID; PD;
D O I：
10.1007/s10562-013-1069-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The gas-phase maleic anhydride hydrogenation was studied at 170 A degrees C and 1 bar using Ni/SiO2-Al2O3 catalysts varying metal loading. The maximum gamma-butyrolactone selectivity was reached for a 10 wt% nickel load. On the basis of temperature programmed experiments, it is proposed that new active sites in selective succinic anhydride hydrogenolysis are formed when Ni loads are higher than 8 wt%.
引用
收藏
页码：1067 / 1073
页数：7
相关论文
共 50 条
  • [1] Gas-Phase Maleic Anhydride Hydrogenation Over Ni/SiO2–Al2O3 Catalysts: Effect of Metal Loading
    C. I. Meyer
    S. A. Regenhardt
    M. E. Bertone
    A. J. Marchi
    T. F. Garetto
    Catalysis Letters, 2013, 143 : 1067 - 1073
  • [2] Highly Selective Cu-Modified Ni/SiO2-Al2O3 Catalysts for the Conversion of Maleic Anhydride to γ-Butyrolactone in Gas Phase
    Bertone, M. E.
    Regenhardt, S. A.
    Meyer, C. I.
    Sebastian, V.
    Garetto, T. F.
    Marchi, A. J.
    TOPICS IN CATALYSIS, 2016, 59 (2-4) : 159 - 167
  • [3] Hydrogenation of Maleic Anhydride to Succinic Anhydride over Ni/HY-Al2O3
    Li, Jie
    Tian, Wei-ping
    Shi, Li
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (22) : 11837 - 11840
  • [4] Gas-phase hydrogenation of maleic anhydride to γ-butyrolactone at atmospheric pressure over Cu-CeO2-Al2O3 catalyst
    Yu, Yang
    Guo, Yanglong
    Zhan, Wangcheng
    Guo, Yun
    Wang, Yanqin
    Wang, Yunsong
    Zhang, Zhigang
    Lu, Guanzhong
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2011, 337 (1-2) : 77 - 81
  • [5] INVESTIGATION OF THE ACIDITY OF NI/AL2O3 AND NI/SIO2-AL2O3 CATALYSTS
    BENBENEK, S
    FEDORYNSKA, E
    WINIAREK, P
    REACTION KINETICS AND CATALYSIS LETTERS, 1993, 51 (01): : 189 - 195
  • [6] Hydrogenation of aromatics over Au-Pd/SiO2-Al2O3 catalysts;: support acidity effect
    Venezia, AM
    La Parola, V
    Pawelec, B
    Fierro, JLG
    APPLIED CATALYSIS A-GENERAL, 2004, 264 (01) : 43 - 51
  • [7] Influence of the support composition on the hydrogenation of acrolein over Ag/SiO2-Al2O3 catalysts
    Volckmar, Claudia E.
    Bron, Michael
    Bentrup, Ursula
    Martin, Andreas
    Claus, Peter
    JOURNAL OF CATALYSIS, 2009, 261 (01) : 1 - 8
  • [8] Maleic anhydride hydrogenation to succinic anhydride over mesoporous Ni/TiO2 catalysts: Effects of Ni loading and temperature
    Torres, Cecilia C.
    Alderete, Joel B.
    Mella, Claudio
    Pawelec, Barbara
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2016, 423 : 441 - 448
  • [9] Gas-phase hydrogenation of maleic anhydride to butyric acid over Cu/TiO2/γ-Al2O3 catalyst promoted by Pd
    Lu, WJ
    Lu, GZ
    Guo, Y
    Guo, YL
    Wang, YS
    CATALYSIS COMMUNICATIONS, 2003, 4 (04) : 177 - 181
  • [10] Competitive Hydrogenation of Benzene in Reformate Gasoline over Ni Supported on SiO2, SiO2-Al2O3, and Al2O3 Catalysts: Influence of Support Nature
    Peyrovi, M. H.
    Rostamikia, T.
    Parsafard, N.
    ENERGY & FUELS, 2018, 32 (11) : 11432 - 11439
12345