Prediction of the enthalpy of vaporization of metals and metalloids

被引：32
|
作者：
Velasco, S.
Román, F. L.
White, J. A.
Mulero, A.
机构：
[1] Univ Salamanca, Dept Fis Aplicada, E-37008 Salamanca, Spain
[2] Univ Salamanca, EPS Zamora, Dept Fis Aplicada, Zamora 49022, Spain
[3] Univ Extremadura, Dept Fis, E-06071 Badajoz, Spain
来源：
FLUID PHASE EQUILIBRIA | 2006年 / 244卷 / 01期
关键词：
enthalpy of vaporization; predictive models; phase transitions; metals; metalloids;
D O I：
10.1016/j.fluid.2006.03.017
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
A simple correlation equation without adjustable parameters is used to obtain the enthalpy of vaporization of 10 metals and 2 metalloids as a function of the temperature. Besides the critical temperature, this equation requires knowing of the enthalpy of vaporization at two reference temperatures: the lowest available temperature and the normal boiling temperature. Average relative deviations are less than 0.75% for the available ranges of temperature. A comparison is made with three other well-known empirical equations based only on the normal boiling point. (c) 2006 Elsevier B.V. All rights reserved.
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页码：11 / 15
页数：5
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