Rhodium-catalyzed direct aldol condensation of ketones: a facile synthesis of fused aromatic compounds

被引:15
|
作者
Terai, H [1 ]
Takaya, H [1 ]
Naota, T [1 ]
机构
[1] Osaka Univ Machikaneyama, Dept Chem, Grad Sch Engn Sci, Toyonaka, Osaka 5608531, Japan
关键词
aldol condensation; rhodium catalyst;
D O I
10.1016/j.tetlet.2006.01.041
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Cationic rhodium complex [Cp*Rh(eta(6)-C6H6)](BF4)(2) (1) acts as an efficient catalyst for direct aldol condensation of ketones. The method can be applied to one-pot synthesis of fused aromatic compounds from cyclic ketones via sequential C-C bond formations. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1705 / 1708
页数:4
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