Active ruthenium-(N-heterocyclic carbene) complexes for hydrogenation of ketones

被引：89

作者：

Yigit, Murat

Yigit, Beyhan

Ozdemir, Ismail ^{[1
]}

Cetinkaya, Engin

Cetinkaya, Bekir

机构：

[1] Inonu Univ, Fac Sci & Art, Dept Chem, TR-44280 Malatya, Turkey

[2] Ege Univ, Dept Chem, Fac Sci, TR-3510 Bornova, Turkey

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2006年 / 20卷 / 05期

关键词：

imidazolin-2-ylidene; N-heterocyclic carbene; benzimidazolin-2-ylidene; transfer hydrogenation;

D O I：

10.1002/aoc.1054

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Four ruthenium-N-heterocyclic carbene complexes (3-6) have been prepared and the new compounds characterized by C, H, N analyses, H-1-NMR and C-13-NMR. The reduction of ketones to alcohols via transfer hydrogenation was achieved with catalytic amounts of complexes 3-6 in the presence of t-BuOK. Copyright (c) 2006 John Wiley & Sons, Ltd.

引用

页码：322 / 327

页数：6

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