Angular and distance dependence of the magnetic properties of oxo-bridged iron(III) dimers

被引：219
|
作者：
Weihe, H
Gudel, HU
机构：
[1] Dept. of Chemistry and Biochemistry, University of Bern, CH-3000 Bern 9
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1997年 / 119卷 / 28期
关键词：
D O I：
10.1021/ja970320r
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The magnetic properties of ore-bridged oxo-(carboxylato)-bridged and oxo-bis(carboxylato)-bridged iron(III) dimers are found to depend on the iron-(mu-O) distance as well as on the iron-(mu-O)-iron angle. With an angular and radial overlap model we account for both these dependencies. The use of an angular overlap model allows us to separate the sigma donor properties of oxide as a ligand into the s sigma and p sigma contributions.
引用
收藏
页码：6539 / 6543
页数：5
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