Hydrothermal synthesis and crystal structure of a novel rare-earth tungsten phosphate supramolecular compound

被引:0
|
作者
Shu, Qi-Xia [1 ]
Sun, Guo-Yuan [2 ]
Wang, Xiao-Bo [1 ]
Hu, Xue-Lei [1 ]
机构
[1] Wuhan Inst Technol, Key Lab Green Chem Proc, Minist Educ, Hubei Key Lab Novel Chem Reactor & Green Chem Tec, Wuhan 430073, Peoples R China
[2] N China Univ Water Conservancy & Elect Power, Sch Mech Engn, Zhengzhou 450011, Peoples R China
关键词
Hydrothermal synthesis; Polyoxometalates; Crystal structure; COMPLEXES; DAWSON;
D O I
10.1016/j.inoche.2012.04.007
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new polyoxometalate (H(2)bpy)(2){Eu(H2O)(3)(PW11O39)}center dot 6H(2)O 1 constructed from lacunary Keggin frameworks, has been hydrothermally synthesized and characterized by IR and X-ray single crystal diffraction. It is interesting to find that the heteropolyanions are linked to chains, and the chains are further connected into an extensive two dimension (2D) layer structure depending on hydrogen bond. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:47 / 49
页数:3
相关论文
共 50 条
  • [1] Synthesis, crystal growth and structure investigations of rare-earth disilicates and rare-earth oxyapatites
    Christensen, AN
    Hazell, RG
    Hewat, AW
    ACTA CHEMICA SCANDINAVICA, 1997, 51 (01): : 37 - 43
  • [2] HYDROTHERMAL CRYSTAL SYNTHESIS AND CRYSTALLOGRAPHIC PROPERTIES OF SOME RARE-EARTH TUNGSTATES
    KHARCENK.LJ
    KLEVCOV, PV
    ACTA CRYSTALLOGRAPHICA, 1966, S 21 : A261 - &
  • [3] Hydrothermal synthesis of rare-earth fluoride nanocrystals
    Wang, Xun
    Zhuang, Jing
    Peng, Qing
    Li, Yadong
    INORGANIC CHEMISTRY, 2006, 45 (17) : 6661 - 6665
  • [4] HYDROTHERMAL SYNTHESIS OF RUBIDIUM RARE-EARTH TUNGSTATES
    KHARCHENKO, LY
    KLEVTSOV, PV
    KRISTALLOGRAFIYA, 1972, 17 (03): : 694 - +
  • [5] Hydrothermal synthesis of doped rare-earth fluorides
    Colon, Evy B.
    Kolis, Joseph W.
    Stepleton, Seth E.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [6] Synthesis and Applications of Rare-Earth Compound Nanotubes
    Yada, Mitsunori
    INORGANIC AND METALLIC NANOTUBULAR MATERIALS: RECENT TECHNOLOGIES AND APPLICATIONS, 2010, 117 : 97 - 115
  • [7] HYDROTHERMAL PREPARATION OF RARE-EARTH HYDROXYCARBONATES - CRYSTAL-STRUCTURE OF NDOHCO3
    CHRISTEN.AN
    ACTA CHEMICA SCANDINAVICA, 1973, 27 (08): : 2973 - 2982
  • [8] SYNTHESIS OF RARE-EARTH CARBONATES UNDER HYDROTHERMAL CONDITIONS
    CHAI, BHT
    MROCZKOWSKI, S
    JOURNAL OF CRYSTAL GROWTH, 1978, 44 (01) : 84 - 97
  • [9] New Insights in the Hydrothermal Synthesis of Rare-Earth Carbonates
    Spiridigliozzi, Luca
    Ferone, Claudio
    Cioffi, Raffaele
    Bortolotti, Mauro
    Dell'Agli, Gianfranco
    MATERIALS, 2019, 12 (13)
  • [10] Hydrothermal synthesis, crystal structure and properties of a new cyanide-containing supramolecular compound
    Bie, HY
    Yu, JH
    Chu, DQ
    Xu, JQ
    Lu, J
    Sun, YH
    Cui, XB
    Li, Y
    Zhang, X
    POLISH JOURNAL OF CHEMISTRY, 2004, 78 (11-12) : 1969 - 1978