The first push-pull μ-nitrido iron phthalocyanine dimer

被引：7
|
作者：
Isci, Umit [1 ]
机构：
[1] Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Turkey
来源：
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2013年 / 17卷 / 10期
关键词：
phthalocyanine; mu-nitrido dimer; diiron; push-pull; BRIDGED DIIRON PHTHALOCYANINE; METALLOPHTHALOCYANINE FUNCTIONALIZED SILICAS; ELECTRON-WITHDRAWING SUBSTITUENTS; NONLINEAR-OPTICAL PROPERTIES; 2 CATALYTIC SITES; SELECTIVE OXIDATION; AROMATIC-COMPOUNDS; METAL-COMPLEXES; BEARING; METHANE;
D O I：
10.1142/S1088424613500880
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first push-pull mu-nitrido diiron phthalocyanine complex was prepared and characterized. The EPR spectrum confirms the Fe+3.5-N-Fe+3.5 formalism. The stability of this dimer in oxidant media (up to 1000 equivalent of H2O2) was studied by UV-vis spectroscopy. The push-pull mu-nitrido diiron phthalocyanine exhibited excellent stability because of the delocalization of an unpaired electron.
引用
收藏
页码：1022 / 1026
页数：5
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