Diastereo-differentiation during 2,4-pentanediol tethered Simmons-Smith type cyclopropanation: Reaction species of hydroxyl group directed zinc carbenoid addition

被引：0

作者：

Sugimura, T ^{[1
]}

Yoshikawa, M ^{[1
]}

Mizuguchi, M ^{[1
]}

Tai, A ^{[1
]}

机构：

[1] Himeji Inst Technol, Fac Sci, Kamigori, Hyogo 6781297, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 08期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The predominant formation methods for the diastereodifferentiating species of zinc carbenoid addition to the 1-cyclohexenyl ether carrying the 2,4-pentanediol moiety were established. The species were found to include two zinc atoms and one carbenoid carbon at the hydroxyl group.

引用

页码：831 / 832

页数：2

共 2 条

[1] DIASTEREO-DIFFERENTIATING SIMMONS-SMITH REACTION USING 2,4-PENTANEDIOL AS A CHIRAL AUXILIARY
SUGIMURA, T
FUTAGAWA, T
TAI, A
TETRAHEDRON LETTERS, 1988, 29 (45) : 5775 - 5778
[2] Hydroxy direction of zinc carbenoid addition to a remote olefin. Analysis and improvement of 2,4-pentanediol tethered Furukawa cyclopropanation
Sugimura, T
Futagawa, T
Yoshikawa, M
Katagiri, T
Miyashige, R
Mizuguchi, M
Nagano, S
Sugimori, S
Tai, A
Tei, T
Okuyama, T
TETRAHEDRON, 2001, 57 (35) : 7495 - 7499

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