Catalytic ship-in-a-bottle assembly within hollow porous nanocapusles

被引：9

作者：

Ehterami, Nasim ^{[1
]}

Dergunov, Sergey A. ^{[1
]}

Ussipbekova, Yenlik ^{[2
]}

Birman, Vladimir B. ^{[3
]}

Pinkhassik, Eugene ^{[1
]}

机构：

[1] St Louis Univ, Dept Chem, St Louis, MO 63103 USA

[2] al Farabi Kazakh Natl Univ, Fac Chem & Chem Technol, Alma Ata 050040, Kazakhstan

[3] Washington Univ, Dept Chem, St Louis, MO 63130 USA

来源：

NEW JOURNAL OF CHEMISTRY | 2014年 / 38卷 / 02期

基金：

美国国家科学基金会;

关键词：

NANOCAPSULES; PROAZAPHOSPHATRANE; TRIMERIZATION; ENTRAPMENT; VESICLES;

D O I：

10.1039/c3nj01449e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Large molecules can be assembled from small components exclusively inside hollow nanocapsules with the help of entrapped catalysts. Phenyl isocyanates enter the capsules through nanopores in the capsule shells and form cyclic trimers that remain entrapped. No assembly happens outside the nanocapsules. Further functionalization of trimers produces functional hierarchical nanomaterials.

引用

页码：481 / 485

页数：5

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