The controlled synthesis of complex hollow nanostructures and prospective applications

被引:45
|
作者
Soares, Sofia F. [1 ,2 ]
Fernandes, Tiago [1 ,2 ]
Daniel-da-Silva, Ana L. [1 ,2 ]
Trindade, Tito [1 ,2 ]
机构
[1] Univ Aveiro, Dept Chem, P-3801193 Aveiro, Portugal
[2] Univ Aveiro, CICECO Aveiro Inst Mat, P-3801193 Aveiro, Portugal
关键词
hollow; nanostructures; hard-templating; soft-templating; self-templating; MESOPOROUS SILICA NANOSPHERES; HIGH-PERFORMANCE; FACILE SYNTHESIS; DRUG-DELIVERY; FIBER MEMBRANES; GENERAL FORMATION; HYBRID MATERIALS; HIGH-CAPACITY; SPHERES; NANOPARTICLES;
D O I
10.1098/rspa.2018.0677
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Functionality in nanoengineered materials has been usually explored on structural and chemical compositional aspects of matter that exist in such solid materials. It is well known that the absence of solid matter is also relevant and the existence of voids confined in the nanostructure of certain particles is no exception. Indeed, over the past decades, there has been great interest in exploring hollow nanostructured materials that besides the properties recognized in the dense particles also provide empty spaces, in the sense of condensed matter absence, as an additional functionality to be explored. As such, the chemical synthesis of hollow nanostructures has been driven not only for tailoring the size and shape of particles with well-defined chemical composition, but also to achieve control on the type of hollowness that characterize such materials. This review describes the state of the art on late developments concerning the chemical synthesis of hollow nanostructures, providing a number of examples of materials obtained by distinct strategies. It will be apparent by reading this progress report that the absence of solid matter determines the functionality of hollow nanomaterials for several technological applications.
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页数:33
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