Yellow-Emitting Y3Si6N11: Ce3+Phosphors for White Light-Emitting Diodes (LEDs)

被引:18
|
作者
Liu, Lihong [1 ,2 ,3 ]
Xie, Rong-Jun [2 ]
Li, Wanyuan [1 ]
Hirosaki, Naoto [2 ]
Yamamoto, Yoshinobu [2 ]
Sun, Xudong [3 ]
机构
[1] Chinese Acad Sci, Struct & Funct Integrat Ceram Grp, Div Funct Mat & Nanodevices, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China
[2] Natl Inst Mat Sci, Sialon Grp, Sialon Unit, Tsukuba, Ibaraki 3050044, Japan
[3] Northeastern Univ, Key Lab Anisotropy & Texture Mat, Minist Educ, Sch Met & Mat, Shenyang 110004, Liaoning, Peoples R China
基金
中国国家自然科学基金;
关键词
LUMINESCENCE PROPERTIES; CONVERSION PHOSPHORS; ALPHA-SIALON; PHOTOLUMINESCENCE; OXYNITRIDE; EARTH; CA; SR; BA;
D O I
10.1111/jace.12357
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A novel Y3-xSi6N11: xCe3+ yellow phosphor was synthesized using the carbothermal reduction and nitridition method at 1550 degrees C for 16h in this letter. Photoluminescence spectra indicated that the phosphor showed broad excitation spectrum and had strong absorption in range of 350-450nm. It also gave a broad emission band (Full width at half maximum=153nm) centered at 575nm under 425-nm excitation. With increasing Ce3+ concentration, the strongest emission intensity was obtained at 5mol% Ce3+ doping amount and a systematic redshift was observed as the Ce3+ concentration increased. The results indicate that this novel yellow phosphor is a promising candidate for using in blue-chip-excited white light-emitting diodes (LEDs).
引用
收藏
页码:1688 / 1690
页数:3
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