Maier-Saupe and Onsager approaches as limits of the nematic-isotropic phase transition

被引:2
|
作者
Simoes, M [1 ]
Pazeti, M [1 ]
Domiciano, SM [1 ]
机构
[1] Univ Estadual Londrina, Dept Fis, BR-86051970 Londrina, PR, Brazil
来源
PHYSICAL REVIEW E | 2002年 / 65卷 / 01期
关键词
D O I
10.1103/PhysRevE.65.011707
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
Through a virial expansion, the long and small range properties of the interaction between ellipsoidal nematic molecules are put together in a unique approach that combines the essentials: of some classical models that describe the nematic-isotropic phase transition. The Lennard-Jones potential that mediates the interaction between the centers of the mass of molecules, the long range Maier-Saupe interaction that favors their alignment and the molecular hard core that hinders their close approximation, as in the Onsager model, are combined in a unique approach that exhibits two phases transitions the gaseous-liquid transition and the nematic-isotropic phase transition. As a conclusion, the Onsager and Maier-Saupe approaches were considered limits of the actual physical situation.
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页码:1 / 011707
页数:6
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