Nitrogen removal from coke making wastewater through a pre-denitrification activated sludge process

被引:24
|
作者
Raper, E. [1 ,2 ]
Fisher, R. [2 ]
Anderson, D. R. [2 ]
Stephenson, T. [1 ]
Soares, A. [1 ]
机构
[1] Cranfield Univ, Water Sci Inst, Cranfield MK43 0AL, Beds, England
[2] Tata Steel, Grp Environm, Swinden Technol Ctr, Rotherham S60 3AR, S Yorkshire, England
基金
英国自然环境研究理事会;
关键词
Coke making wastewater; Nitrification; Denitrification; sCOD:TN ratio; Nitrate-respiring bacteria; POLYCYCLIC AROMATIC-HYDROCARBONS; NITRITE ACCUMULATION; BIOLOGICAL NITROGEN; THIOCYANATE DEGRADATION; COAL-GASIFICATION; CARBON; PLANT; PHENOL; POLLUTANTS; AMMONIUM;
D O I
10.1016/j.scitotenv.2019.02.196
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Under the Industrial Emissions Directive (IED), coke production wastewater must be treated to produce an effluent characterised by a total nitrogen (TN) <50 mg/L. An anoxic-aerobic activated sludge pilot-plant (1 m(3)) fed with coke production wastewater was used to investigate the optimal operational requirements to achieve such an effluent. The loading rates applied to the pilot-plant varied between 0.198-0.418 kg COD/m(3).day and 0.029-0.081 kg TN/m(3).day, respectively. The ammonia (NH4+-N) removals were maintained at 96%, after alkalinity addition. tinder all conditions, phenol and SCN remained stable at 96% and 100%, respectively with both being utilised as carbon sources during clenitrification. The obtained results showed that influent soluble chemical oxygen demand (sCOD) to TN ratio of should be maintained at >5.7 to produce an effluent TN <50 mg/L. Furthermore, nitrite accumulation was observed under all conditions indicating a disturbance to the denitrification pathway. Overall, the anoxic-aerobic activated sludge process was shown to be a robust and reliable technology to treat coke making wastewater and achieve the LED requirements. Nevertheless, the influent to the anoxic tank should be monitored to ensure a sCOD:TN ratio >5.7 or, alternately, the addition of an external carbon source should be considered. (C) 2019 Elsevier B.V. All rights reserved.
引用
收藏
页码:31 / 38
页数:8
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