Transesterification of jatropha curcas oil to biodiesel by using short necked clam (orbicularia orbiculata) shell derived catalyst

被引：26
|
作者：
Taufiq-Yap, Y. H. [1 ,2 ]
Lee, H. V. [1 ,2 ]
Lau, P. L. [1 ,2 ]
机构：
[1] Univ Putra Malaysia, Fac Sci, Ctr Excellence Catalysis Sci & Technol, Upm Serdang 43400, Selangor, Malaysia
[2] Univ Putra Malaysia, Fac Sci, Dept Chem, Upm Serdang 43400, Selangor, Malaysia
来源：
ENERGY EXPLORATION & EXPLOITATION | 2012年 / 30卷 / 05期
关键词：
CaO; Waste shell; FAME; Methanolysis; Heterogeneous catalyst; SOYBEAN OIL; CALCIUM-OXIDE; WASTE; BASE; FUEL;
D O I：
10.1260/0144-5987.30.5.853
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Investigation has been conducted to develop an environmental friendly and economically feasible process for biodiesel production. Natural short necked clam shell was utilized as calcium oxide (CaO) source for transesterification of non-edible Jatropha curcas oil to biodiesel. The powdered clam shell was calcined at 900 degrees C for 3 h to transform calcium carbonate (CaCO3) in shell to active CaO catalyst. The effect of catalyst loading, methanol to oil molar ratio and reaction time on fatty acid methyl ester (FAME) yield was investigated. Under optimal condition, biodiesel yield achieved 93% within 6 h at 65 degrees C. As a result, the catalytic activity of waste clam shell-derived catalyst is comparable to commercial CaO catalyzed reaction. Hence, it can be used as another renewable yet cost-effective catalyst source for biodiesel production.
引用
收藏
页码：853 / 866
页数：14
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