Hydrothermal Syntheses, Crystal Structures and Thermal Properties of Two New Organically Templated Open-framework Gallium Phosphites

被引：4
|
作者：
Zhou Guang-peng [1 ,2 ]
Yang Yu-lin [1 ]
Fan Rui-qing [1 ]
Xie Jia-qing [2 ]
Quan Xue-jun [2 ]
机构：
[1] Harbin Inst Technol, Dept Chem, Harbin 150001, Peoples R China
[2] Chongqing Univ Technol, Coll Chem & Chem Engn, Chongqing 400050, Peoples R China
来源：
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2013年 / 29卷 / 02期
基金：
黑龙江省自然科学基金; 中国国家自然科学基金;
关键词：
Hydrothermal synthesis; Crystal structure; Gallium phosphite; MAGNETIC-PROPERTIES; METAL PHOSPHATES; BUILDING UNIT; GA/P RATIO; DIETHYLENETRIAMINE; CHANNELS; LAYER; RINGS; DETA;
D O I：
10.1007/s40242-013-2212-x
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two new open-framework gallium phosphites formulated as (C2N2H10)(0.5)Ga-2(OH)(H2O)(HPO3)(3)(1) and (C3N2H5)(2)(C3N2H6)Ga-8(H2O)(6)(HPO3)(14)(2) were hydrothermally synthesized in the presence of ethylenediamine(en) and imidazole 8 structure directing agents(SDA), respectively. Structural analyses reveal that the 3D structures of compounds 1 and 2 are both built up from the linkage of GaO6, GaO5(H2O) and HPO32- units by sharing vertices. The structure of compound 2 is constructed from well-known 4.6.12-net connecting layers in the AAAA stacking sequence, which are penetrated by the 1D Ga-O-P chains to form a 3D pillared-layered structure.
引用
收藏
页码：201 / 205
页数：5
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