Au decorated Fe3O4@TiO2 magnetic composites with visible light-assisted enhanced catalytic reduction of 4-nitrophenol

被引:57
|
作者
Zhou, Ying [1 ]
Zhu, Yihua [1 ]
Yang, Xiaoling [1 ]
Huang, Jianfei [1 ]
Chen, Wei [1 ]
Lv, Xiaoming [1 ]
Li, Cuiyan [1 ]
Li, Chunzhong [1 ]
机构
[1] E China Univ Sci & Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Ultrafine Mat, Shanghai 200237, Peoples R China
来源
RSC ADVANCES | 2015年 / 5卷 / 62期
基金
中国国家自然科学基金;
关键词
AG NANOPARTICLES; P-NITROPHENOL; HETEROGENEOUS PHOTOCATALYSIS; AU/TIO2; NANOCOMPOSITES; GOLD NANOPARTICLES; CARBON-MONOXIDE; NANOSTRUCTURES; DEGRADATION; IRRADIATION; CONVERSION;
D O I
10.1039/c5ra08243a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Heterostructured Au nanoparticle decorated Fe3O4@TiO2 composite magnetic microspheres (MSs) were synthesized by grafting Au nanoparticles onto 3-aminopropyltrimethoxysilane (APTMS) modified Fe3O4@TiO2 MSs. Significantly, by varying the reaction conditions, the as-synthesized Fe3O4@TiO2@Au MSs showed high performance in the catalytic reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4AP) in the presence of NaBH4 under visible light. In addition, the as-prepared Fe3O4@TiO2@Au MSs can clean themselves by photocatalytic degradation of organic molecules, and can be reused for several cycles with convenient magnetic separability. This approach provided a platform based on the synergy of varying components under suitable conditions to optimize the catalytic ability.
引用
收藏
页码:50454 / 50461
页数:8
相关论文
共 50 条
  • [1] Au/Fe3O4@TiO2 hollow nanospheres as efficient catalysts for the reduction of 4-nitrophenol and photocatalytic degradation of rhodamine B
    Jinchun Cheng
    Shiling Zhao
    Wenbin Gao
    Pengbo Jiang
    Rong Li
    Reaction Kinetics, Mechanisms and Catalysis, 2017, 121 : 797 - 810
  • [2] Au/Fe3O4@TiO2 hollow nanospheres as efficient catalysts for the reduction of 4-nitrophenol and photocatalytic degradation of rhodamine B
    Cheng, Jinchun
    Zhao, Shiling
    Gao, Wenbin
    Jiang, Pengbo
    Li, Rong
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2017, 121 (02) : 797 - 810
  • [3] Photocatalytic reduction of Cr(Ⅵ) by magnetic nanomaterial Fe3O4@TiO2 under visible light
    Wang Z.
    Wang Y.
    Xiao G.
    Su H.
    Huagong Xuebao/CIESC Journal, 2019, 70 (10): : 4062 - 4071
  • [4] Environmentally benign magnetic chitosan/Fe3O4 composites as reductant and stabilizer for anchoring Au NPs and their catalytic reduction of 4-nitrophenol
    Qiu, Yunfeng
    Ma, Zhuo
    Hu, PingAn
    JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (33) : 13471 - 13478
  • [5] Ag-Fe2O3 nanocomposites with enhanced catalytic activity for reduction of 4-nitrophenol
    Liu, Shiben
    Chen, Yingjie
    Dong, Lifeng
    MATERIALS RESEARCH EXPRESS, 2016, 3 (07):
  • [6] Facile synthesis of bifunctional Fe3O4/Au nanocomposite and their application in catalytic reduction of 4-nitrophenol
    Yan, Feng
    Sun, Rongyan
    MATERIALS RESEARCH BULLETIN, 2014, 57 : 293 - 299
  • [7] Green synthesis of Au decorated CoFe2O4 nanoparticles for catalytic reduction of 4-nitrophenol and dimethylphenylsilane oxidation
    Saire-Saire, Samuel
    Barbosa, Eduardo C. M.
    Garcia, Daniel
    Andrade, Leandro H.
    Garcia-Segura, Sergi
    Camargo, Pedro H. C.
    Alarcon, Hugo
    RSC ADVANCES, 2019, 9 (38) : 22116 - 22123
  • [8] A systematic study on Au-PDA@Fe3O4 core-shell catalysts for enhanced catalytic reduction of 4-nitrophenol
    Sun, Libo
    Xie, Qingtai
    Jing, Heshun
    Xie, Jindong
    Tan, Wenyu
    Duan, Baorong
    Sun, Xun
    Qi, Caixia
    Su, Huijuan
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2024, 703
  • [9] Magnetic Fe3O4@MIL-100(Fe) core-shells decorated with gold nanoparticles for enhanced catalytic reduction of 4-nitrophenol and degradation of azo dye
    Aslam, Sobia
    Subhan, Fazle
    Liu, Zhen
    Yan, Zifeng
    Ahmad, Abrar
    Nazir, Afaq
    Siddiqa, Ayesha
    Yaseen, Muhammad
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2023, 660
  • [10] Enhanced Catalytic Reduction of 4-Nitrophenol Driven by Fe3O4-Au Magnetic Nanocomposite Interface Engineering: From Facile Preparation to Recyclable Application
    Chen, Yue
    Zhang, Yuanyuan
    Kou, Qiangwei
    Liu, Yang
    Han, Donglai
    Wang, Dandan
    Sun, Yantao
    Zhang, Yongjun
    Wang, Yaxin
    Lu, Ziyang
    Chen, Lei
    Yang, Jinghai
    Xing, Scott Guozhong
    NANOMATERIALS, 2018, 8 (05):