LIQUID PHASE HYDROGEN TRANSFER TO CYCLOPENTANONE OVER MgO-I2 AND MgO-RI CATALYSTS

被引：5
|
作者：
Glinski, Marek [1 ]
Ulkowska, Urszula [1 ]
机构：
[1] Warsaw Univ Technol Politechn, Fac Chem, PL-00664 Warsaw, Poland
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 2008年 / 95卷 / 01期
关键词：
Hydrogen transfer; cyclopentanone; magnesium oxide; aldol condensation;
D O I：
10.1007/s11144-008-5286-6
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Instead of cyclopentanol, 2-cyclopentylidene-cyclopentanone is the main product of liquid phase hydrogen transfer from secondary alcohols to cyclopentanone in the presence of pure MgO [1]. In the present work it has been shown that a significant increase in the selectivity towards cyclopentanol has been observed for MgO treated with I-2 or alkyl iodides.
引用
收藏
页码：107 / 112
页数：6
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