Mean-field nematic-smectic-A transition in a random polymer network

被引:27
|
作者
Olmsted, PD
Terentjev, EM
机构
[1] UNIV CAMBRIDGE,CAVENDISH LAB,CAMBRIDGE CB3 0HE,ENGLAND
[2] UNIV LEEDS,DEPT PHYS,LEEDS LS2 9JT,W YORKSHIRE,ENGLAND
来源
PHYSICAL REVIEW E | 1996年 / 53卷 / 03期
关键词
D O I
10.1103/PhysRevE.53.2444
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
Liquid-crystal elastomers present a rich combination of effects associated with orientational symmetry breaking and the underlying rubber elasticity. In this work we focus on the effect of the network on the nematic-smectic-A transition, exploring the additional translational symmetry breaking in these elastomers. We incorporate the crosslinks as a random field in a microscopic picture, thus expressing the degree to which the smectic order is locally frozen with respect to the network. We predict a modification of the NA transition, notably that it can be treated at the mean-field level (type-I system), due to the coupling with elastic degrees of freedom. There is a shift in the transition temperature T-NA, a suppression of the Halperin-Lubensky-Ma effect (thus recovering the mean-field continuous transition to the smectic state), and a new tricritical point, depending on the conditions of network formation. When the nematic phase possesses ''soft elasticity,'' the NA transition become's of first order due to the coupling with soft phonons in the network. We also discuss the microscopic origin of the phenomenological long-wavelength coupling between smectic phase and elastic strain.
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页码:2444 / 2453
页数:10
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