A novel twin-tailed hydrophobically associating copolymer: synthesis, characterization and solution properties

被引：6
|
作者：
Kuang, Wei [1 ,2 ]
Zhang, Jian [3 ]
Li, Ruyin [3 ]
Wu, Bo [1 ]
Tan, Yebang [1 ]
机构：
[1] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Shandong, Peoples R China
[2] Shandong Polytech Univ, Sch Chem & Pharmaceut Engn, Jinan 250353, Peoples R China
[3] CNOOC Res Ctr, Technol Res Dept, State Key Lab Offshore Oil Exploitat, Beijing 100027, Peoples R China
来源：
POLYMER BULLETIN | 2013年 / 70卷 / 12期
关键词：
Water-soluble polymer; Hydrophobic association; Amphiphile; Polyelectrolyte; WATER-SOLUBLE POLYMERS; SOLUTION BEHAVIOR; MODIFIED POLYACRYLAMIDES; AGGREGATION BEHAVIOR; LIGHT-SCATTERING; DILUTE-SOLUTION; ACRYLAMIDE; MICROSTRUCTURE; POLYMERIZATION; SURFACTANT;
D O I：
10.1007/s00289-013-1039-4
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Novel twin-tailed hydrophobically associating copolymers (DDSPAM) were prepared by micellar copolymerization of acrylamide (AM) and sodium vinylsulfonate with N,N-didecyl-N-methyl-N-(4-vinylbenzyl)ammonium chloride in an aqueous solution. The structure and composition of DDSPAM were characterized by H-1-NMR and elemental analysis. While the molecular weights of the copolymers were obtained via static light scattering, the hydrodynamic radius of aggregates was investigated using dynamic light scattering. The critical micellar concentration cmc and gamma (cmc) values of DDSPAM were measured using fluorescence and later correlated with the values obtained from surface tension measurements. In addition, the viscosity stability studies of DDSPAM and hydrolyzed polyacrylamide (HPAM) revealed that DDSPAM, with twin tails of hydrophobic groups, exhibited better salt tolerance as well as temperature resistance compared to HPAM.
引用
收藏
页码：3547 / 3562
页数：16
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