4-OH-TEMPO/TCQ/TBN/HCl: A Metal-Free Catalytic System for Aerobic Oxidation of Alcohols under Mild Conditions

被引：7
|
作者：
Dong, Yanli [1 ]
Zhao, Xiaomei [1 ]
Liu, Renhua [1 ]
机构：
[1] E China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2015年 / 33卷 / 09期
基金：
国家高技术研究发展计划(863计划); 中国国家自然科学基金;
关键词：
oxidation of alcohols; transition-metal-free; green and economical; HIGHLY-ACTIVE ORGANOCATALYST; CARBONYL-COMPOUNDS; MOLECULAR-OXYGEN; EFFICIENT; EQUIVALENT; ALDEHYDES; AZADO;
D O I：
10.1002/cjoc.201500357
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A green and economical catalyst system, 4-OH-TEMPO/TCQ/TBN/HCl, for the aerobic oxidation of a broad range of primary and secondary alcohols to the corresponding carbonyl compounds has been developed. These reactions proceed without transition-metals under mild conditions with excellent yields.
引用
收藏
页码：1019 / 1023
页数：5
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