Relative reactivities in vinyl copolymerization

被引：4

作者：

Alfrey, T ^{[1
]}

Price, CC ^{[1
]}

机构：

[1] UNIV NOTRE DAME,DEPT CHEM,NOTRE DAME,IN 46556

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1996年 / 34卷 / 02期

关键词：

D O I：

10.1002/pola.1996.807

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

From data in tire literature on relative rates of copolymerization it has been possible to evaluate two constants, Q and e, characteristic of an individual monomer, which appear to account satisfactorily for its behavior in copolymerization, The constant Q describes the ''general monomer reactivity'' and is apparently related to possibilities for stabilization in a radical adduct. The constant e labs account of polar factors influencing copolymerization.

引用

页码：157 / 162

页数：6

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