Metal-Free Oxidative C-H Amination of 8-Acylaminoquinolines and Anilides with N-Fluorobenzenesulfonimide

被引：47
|
作者：
Wang, Yang [1 ,2 ]
Wang, Ying [1 ,2 ]
Guo, Zhenyu [1 ,2 ]
Zhang, Qian [1 ,2 ]
Li, Dong [2 ]
机构：
[1] Hubei Univ Technol, Hubei Collaborat Innovat Ctr High Efficiency Util, Wuhan 430068, Peoples R China
[2] Hubei Univ Technol, Sch Mat & Chem Engn, Wuhan 430068, Peoples R China
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 5卷 / 12期
基金：
中国国家自然科学基金;
关键词：
amination; hypervalent compounds; iodine; metal-free; n-fluorobenzenesulfonimide; PALLADIUM-CATALYZED DIAMINATION; BOND-FORMATION; PHENYLIODINE(III) BIS(TRIFLUOROACETATE); FUNCTIONAL MOLECULES; AMBIENT-TEMPERATURE; AROMATIC-COMPOUNDS; CHEMICAL-SYNTHESIS; GREEN CHEMISTRY; NITROGEN; ALKENES;
D O I：
10.1002/ajoc.201600389
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An oxidative C-H amination of 8-acylaminoquinolines and anilides with N-fluorobenzenesulfonimide (NFSI) has been developed. This process was mediated by a hypervalent iodine reagent PhI(OPiv)(2) under mild reaction conditions without any metallic catalyst or oxidant. The protocol showed good air and moisture tolerance, functional groups compatibility, and gave the highly site-selective amination products in moderate to good yields, providing a novel and facile method for synthesis of arylamine compounds.
引用
收藏
页码：1438 / 1441
页数：4
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