Selective Visible-Light Photocatalytic Aerobic Oxidation of Alkenes to Epoxides with Pd/ZnO Nanoparticles

被引：12
|
作者：
Hosseini-Sarvari, Mona [1 ]
Bazyar, Zahra [1 ]
机构：
[1] Shiraz Univ, Dept Chem, Shiraz 7194684795, Iran
来源：
CHEMISTRYSELECT | 2020年 / 5卷 / 28期
基金：
美国国家科学基金会;
关键词：
photoepoxidation; epoxidation; Pd; ZnO nanoparticles; pharmaceutics; biologically; CROSS-COUPLING REACTIONS; EPOXIDATION; OLEFINS; ACID;
D O I：
10.1002/slct.202002401
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
One of the old challenges for the selective synthesis of epoxides is the epoxidation of different alkenesviamolecular oxygen (air) under moderate conditions. Herein, we report that Pd/ZnO nanoparticles as a photocatalyst could be catalyzed the aerobic epoxidation of a broad range of alkenes by molecular oxygen (air) under visible light irradiation at room temperature. Besides, to show the applicability and benefit of the medicinal chemistry of the present method, the epoxidation of selected pharma agents is shown.
引用
收藏
页码：8853 / 8857
页数：5
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