Continuous Gas-Phase Hydroaminomethylation using Supported Ionic Liquid Phase Catalysts

被引：49
|
作者：
Schneider, Martin Johannes [1 ]
Lijewski, Martin [1 ]
Woelfel, Rene [1 ]
Haumann, Marco [1 ]
Wasserscheid, Peter [1 ]
机构：
[1] Univ Erlangen Nurnberg, Dept Chem & Bioengn, D-91058 Erlangen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 27期
关键词：
amine formation; hydroaminomethylation; hydroformylation; ionic liquids; supported catalysts; TANDEM REACTION SEQUENCES; SYNTHETIC APPLICATIONS; ALKENES;
D O I：
10.1002/anie.201301365
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Just SILP-ing through: Hydroaminomethylation of ethylene and diethylamine to diethylpropylamine is demonstrated as a continuous gas-phase reaction (see picture) using a supported ionic liquid phase (SILP) to immobilize the applied homogenous Rh-Xantphos catalyst. Highly selective and long-term stable (18 days) catalyst operation was obtained if the ionic liquid was of low basicity and lipophilicity combined with a porous activated carbon support. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：6996 / 6999
页数：4
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