Sulfuric Acid Functionalized Silica-Coated Magnetic Nanoparticles: Preparation and Application in Synthesis of Mono-, Di- and Tri[bis(6-aminopyrimidinyl)methanes]

被引:22
|
作者
Karimi, Ali Reza [1 ]
Dalirnasab, Zeinab [1 ]
Karimi, Marzie [1 ]
Bagherian, Fatemeh [1 ]
机构
[1] Arak Univ, Fac Sci, Dept Chem, Arak 3815688349, Iran
来源
SYNTHESIS-STUTTGART | 2013年 / 45卷 / 23期
关键词
nanostructures; catalysis; condensation; aldehydes; heterocycles; ultrasound; EFFICIENT; URACILS; DERIVATIVES; CATALYST; RING;
D O I
10.1055/s-0033-1339761
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Sulfuric acid functionalized silica-coated magnetic nanoparticles (SSA-MNPs) were prepared by a simple method and evaluated as efficient catalysts for the condensation reaction of 6-amino-1,3-dimethyluracil with mono-, di-, or trialdehydes to give the corresponding mono-, di- and tri[bis(6-aminopyrimidinyl)methanes]. The catalyst was simply recycled by the use of an external magnetic field and could be reused five times without significant loss of activity or mass.
引用
收藏
页码:3300 / 3304
页数:5
相关论文
共 22 条
  • [1] Alkanedisulfamic Acid Functionalized Silica-Coated Magnetic Nanoparticles: Preparation and Catalytic Investigation in Synthesis of Mono-, Bis- and Tris[bis(4-hydroxycoumarinyl)methanes]
    Karimi, Ali Reza
    Eftekhari, Zahra
    Karimi, Marzie
    Dalirnasab, Zeinab
    SYNTHESIS-STUTTGART, 2014, 46 (23): : 3180 - 3184
  • [2] (Triazinediyl)bis sulfamic acid-functionalized silica-coated magnetite nanoparticles: Preparation, characterization and application as an efficient catalyst for synthesis of mono-, bis-, tris- and spiro-perimidines
    Mohammad Ali Bodaghifard
    Sajad Asadbegi
    Zahra Bahrami
    Journal of the Iranian Chemical Society, 2017, 14 : 365 - 376
  • [3] (Triazinediyl)bis sulfamic acid-functionalized silica-coated magnetite nanoparticles: Preparation, characterization and application as an efficient catalyst for synthesis of mono-, bis-, tris- and spiro-perimidines
    Bodaghifard, Mohammad Ali
    Asadbegi, Sajad
    Bahrami, Zahra
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2017, 14 (02) : 365 - 376
  • [4] Synthesis of Highly Functionalized Piperidines Using Polyphosphoric Acid Supported on Silica-coated Magnetic Nanoparticles
    Khojastehnezhad, Amir
    Maleki, Behrooz
    Karrabi, Behnaz
    Seresht, Esmail Rezaei
    ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 2017, 49 (04) : 338 - 345
  • [5] Synthesis and characterization of mesoporous silica SBA-15 functionalized by mono-, di-, and tri-amine and its catalytic behavior towards Michael addition
    Hakiki, Aboubakr
    Boukoussa, Bouhadjar
    Zahmani, Hadjira Habib
    Hamacha, Rachida
    Abdelkader, Nour el Houda Hadj
    Bekkar, Fadila
    Bettahar, Faiza
    Nunes-Beltrao, Ana Paola
    Hacini, Salih
    Bengueddach, Abdelkader
    Azzouz, Abdelkrim
    MATERIALS CHEMISTRY AND PHYSICS, 2018, 212 : 415 - 425
  • [6] Synthesis of functionalized mono-, di-, tri-, and tetraphosphines: Attempted application to prepare hyperbranched polymers and dendrimers built with phosphines at each branching point
    Huc, V
    Balueva, A
    Sebastian, RM
    Caminade, AM
    Majoral, JP
    SYNTHESIS-STUTTGART, 2000, (05): : 726 - 730
  • [7] Triflic Acid-Functionalized Silica-Coated Magnetic Nanoparticles as a Magnetically Separable Catalyst for Synthesis of gem-Dihydroperoxides
    Liu, Yong-Hui
    Deng, Jia
    Gao, Jian-Wu
    Zhang, Zhan-Hui
    ADVANCED SYNTHESIS & CATALYSIS, 2012, 354 (2-3) : 441 - 447
  • [8] Synthesis of mono- and bis-spiro-2-amino-4H-pyrans catalyzed by S-alkyl O-hydrogen sulfothioate functionalized silica-coated magnetic nanoparticles under ultrasound irradiation
    Karimi, Ali Reza
    Abadi, Reyhaneh Davood
    Dalirnasab, Zeinab
    RESEARCH ON CHEMICAL INTERMEDIATES, 2015, 41 (10) : 7427 - 7435
  • [9] Synthesis of mono- and bis-spiro-2-amino-4H-pyrans catalyzed by S-alkyl O-hydrogen sulfothioate functionalized silica-coated magnetic nanoparticles under ultrasound irradiation
    Ali Reza Karimi
    Reyhaneh Davood Abadi
    Zeinab Dalirnasab
    Research on Chemical Intermediates, 2015, 41 : 7427 - 7435
  • [10] Cu-phthalocyanine Coated Hybrid Magnetic Nanoparticles: Preparation and Application in the Synthesis of Mono- and Bis pyrano[2,3-d]pyrimidinones and mono- and Bis-2-amino-4H-pyrans
    Karimi, Ali Reza
    Bagherian, Fatemeh
    Karimi, Marzie
    IRANIAN JOURNAL OF CHEMISTRY & CHEMICAL ENGINEERING-INTERNATIONAL ENGLISH EDITION, 2020, 39 (02): : 21 - 31