Bio-oil production from hydrogenation liquefaction of rice straw over metal (Ni, Co, Cu)-modified CeO2 catalysts

被引:17
|
作者
Ma, Quanhong [1 ]
Chen, Dongdong [1 ]
Wei, Lingfei [1 ]
Shen, Quanhao [1 ]
Ji, Zhongxiang [1 ]
Chen, Yong [1 ]
Zou, Xiaoyue [1 ]
Xu, Chongjiu [1 ]
Zhou, Jiancheng [1 ]
机构
[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing, Jiangsu, Peoples R China
关键词
bio-oil; hydro-liquefaction; metal/CeO2; oxygen vacancy; rice straw; HYDROTHERMAL LIQUEFACTION; BIOMASS; LIGNIN;
D O I
10.1080/15567036.2017.1409295
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
This paper describes catalytic hydrogenation liquefaction of rice straw over metal (Ni, Co, and Cu)-modified CeO2 catalysts for bio-oil production. The results show that the highest rice straw conversion (89.08%) and bio-oil yield (66.7%) were obtained over Ni/CeO2 catalyst. The bio-oil contains mainly phenols, high-value-added, and widely used chemicals. Furthermore, metal-modified CeO2 catalysts can significantly influence the components of bio-oil with the highest percentage of C7-C10 compounds. This work thus demonstrates that metal/CeO2 catalysts can be effective in improving the bio-oil yield and selectivity in hydro-liquefaction of rice straw into bio-oil.
引用
收藏
页码:200 / 206
页数:7
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