Copper(I) oxide nanoparticles supported on magnetic casein as a bio-supported and magnetically recoverable catalyst for aqueous click chemistry synthesis of 1,4-disubstituted 1,2,3-triazoles

被引：24
|
作者：
Shaabani, Shabnam [1 ]
Tabatabaei, Azadeh Tavousi [1 ]
Shaabani, Ahmad [1 ]
机构：
[1] Shahid Beheshti Univ, Fac Chem, GC, POB 19396-4716, Tehran, Iran
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2017年 / 31卷 / 02期
基金：
美国国家科学基金会;
关键词：
alkyne-azide cycloaddition; bio-supported catalyst; casein; copper(I) oxide nanoparticles; magnetically recoverable nanocatalyst; TRIAZOLES; AZIDES; SIZE;
D O I：
10.1002/aoc.3559
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Copper(I) oxide nanoparticles supported on magnetic casein (Cu2O/Casein@Fe(3)O(4)NPs) has been synthesized as a bio-supported catalyst and was characterized using powder X-ray diffraction, transmission electron microscopy, energy dispersive X-ray and Fourier transform infrared spectroscopies, thermogravimetric analysis and inductively coupled plasma optical emission spectrometry. The catalytic activity of the synthesized catalyst was investigated in one-pot three-component reactions of alkyl halides, sodium azide and alkynes to prepare 1,4-disubstituted 1,2,3-triazoles with high yields in water. The reaction work-up is simple and the catalyst can be magnetically separated from the reaction medium and reused in subsequent reactions.
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页数：6
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