Catalytic cyanosilylation of ketones using organic catalyst 1,1,3,3-tetramethylguanidine

被引：57

作者：

Wang, LJ ^{[1
]}

Huang, X ^{[1
]}

Jiang, J ^{[1
]}

Liu, XH ^{[1
]}

Feng, XM ^{[1
]}

机构：

[1] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Peoples R China

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 10期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/j.tetlet.2005.12.135

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,1,3.3-Tetramethylguanidine acts as a highly effective catalyst for cyanosilylation of various ketones and aldehydes to the corresponding cyanohydrin trimethylsilyl ethers in up to 99% yield. The reaction proceeds smoothly with 0.1 mol % catalyst loading at 25 degrees C under solvent-free conditions. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：1581 / 1584

页数：4

共 50 条

[1] CATALYTIC EFFECTS OF 1,1,3,3-TETRAMETHYLGUANIDINE FOR ISOCYANATE REACTIONS
GEOGHEGAN, JT
ROTH, RW
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1965, 9 (03) : 1089 - +
[2] 1,1,3,3-TETRAMETHYLGUANIDINE - AN EFFICIENT AND SELECTIVE CATALYST FOR THE BENZOYLATION OF ALCOHOLS
KIM, S
CHANG, H
[J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1984, 5 (05) : 205 - 206
[3] 1,1,3,3-TETRAMETHYLGUANIDINE - AN EFFECTIVE CATALYST FOR THE TERT-BUTYLDIMETHYLSILYLATION OF ALCOHOLS
KIM, S
CHANG, H
[J]. SYNTHETIC COMMUNICATIONS, 1984, 14 (10) : 899 - 904
[4] TITRATIONS OF WEAK ACIDS IN 1,1,3,3-TETRAMETHYLGUANIDINE
CARUSO, JA
JONES, GG
POPOV, AI
[J]. ANALYTICA CHIMICA ACTA, 1968, 40 (01) : 49 - &
[5] PROPERTIES OF 1,1,3,3-TETRAMETHYLGUANIDINE AS A NONAGUEOUS SOLVENT
ANDERSON, ML
HAMMER, RN
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1967, 12 (03): : 442 - &
[6] 2-Acetyl-1,1,3,3-tetramethylguanidine
Tiritiris, Loannis
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2996 - +
[7] Thermochemistry of 1,1,3,3-tetramethylguanidine and 1,1,3,3-tetramethylguanidinium nitrate
Vitorino, Joana
Agapito, Filipe
Piedade, M. Fatima M.
Bernardes, Carlos E. S.
Diogo, Herminio P.
Leal, Joao P.
Minas da Piedade, Manuel E.
[J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 2014, 77 : 179 - 189
[8] Application of 1,1,3,3-tetramethylguanidine in the reaction of amino acids with pantolactone
Wlostowski, M
Rowicki, T
Synoradzki, L
[J]. TETRAHEDRON-ASYMMETRY, 2004, 15 (15) : 2333 - 2338
[9] Stable analogs of the uranyl ion containing 1,1,3,3-tetramethylguanidine
Bertke, Jeffrey A.
Bunge, Scott D.
[J]. DALTON TRANSACTIONS, 2007, (41) : 4647 - 4649
[10] Immobilized 1,1,3,3-Tetramethylguanidine Ionic Liquids as the Catalyst for Synthesizing Propylene Glycol Methyl Ether
Liang, Shuguang
Zhou, Yinxi
Liu, Huizhen
Jiang, Tao
Han, Buxing
[J]. CATALYSIS LETTERS, 2010, 140 (1-2) : 49 - 54

← 1 2 3 4 5 →