Crystal Structure of Zinc(II) Complex Containing Pyridine and Its Catalytic Activity of Hydrolysis of p-Nitrophenyl Phosphate

被引：1

作者：

Zhang Yong ^{[1
]}

Xiong Qi-Jei ^{[1
]}

Zhang Nan-Hai ^{[1
]}

Chen Shi-Ming ^{[2
]}

Zhang Ruo-Xuan ^{[1
]}

Ma Zhi-Gang ^{[1
]}

Chen Xue-Mei ^{[1
]}

机构：

[1] Hubei Polytech Univ, Sch Chem & Mat Engn, Huangshi 435003, Hubei, Peoples R China

[2] Huangshi Ctr Hosp, Huangshi 435001, Hubei, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 29卷 / 12期

关键词：

zinc(II) complex; pyridine; crystal structure; catalytic activity; COORDINATION; MECHANISM;

D O I：

10.3969/j.issn.1001-4861.2013.00.345

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A zinc(II) complex [Zn-2(L)Cl-3](2)[ZnCl4] center dot CH3CN center dot CH3OH center dot 3H(2)O (L=1,1,4,7,7-Pentakis (2-pyridyl-methyl) diethylenetriamine) has been synthesized and structurally characterized, and its catalytic activity was investigated by using p-nitrophenyl phosphate(PNPP) as the substrate. The results showed that one zinc(I)) of the complex was coordinated in a distorted trigonal-bipyramidal geometry, and the coordination geometry around another zinc (II) was distorted octahedron. Its catalytic hydrolysis of PNPP was consistent with Michaelis-Mentent model. Several kinetic parameters V-max, K-m and k(cat) were examined under different conditions, and maximal catalytic activity of zinc(II) complex was observed at a temperature of 30 degrees C and pH=8.0. CCDC: 921868.

引用

页码：2555 / 2560

页数：6

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