In situ preparation of a multifunctional chiral hybrid organic-inorganic catalyst for asymmetric multicomponent reactions

被引：28
|
作者：
Garcia-Garcia, Pilar [1 ]
Zagdoun, Alexandre [2 ]
Coperet, Christophe [3 ]
Lesage, Anne [2 ]
Diaz, Urbano [1 ]
Corma, Avelino [1 ]
机构：
[1] Univ Politecn Valencia, UPV CSIC, Inst Tecnol Quim, Valencia 46022, Spain
[2] Univ Lyon, UCB Lyon 1, ENS Lyon, CNRS,Ctr RMN Tres Hauts Champs, F-69100 Villeurbanne, France
[3] ETH, Dept Chem, Inorgan Chem Lab, CH-8093 Zurich, Switzerland
来源：
CHEMICAL SCIENCE | 2013年 / 4卷 / 05期
关键词：
ORGANOCATALYTIC MICHAEL ADDITION; CINCHONA ALKALOID DERIVATIVES; MESOPOROUS ORGANOSILICA; NITROALKENES; MALONATE; POLYMER; ALDOL; IMMOBILIZATION; CYCLOADDITION; SILICA;
D O I：
10.1039/c3sc22310h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A chiral mesoporous organosilica material incorporating a urea based-cinchona derivative and propylamine groups was prepared by a co-condensation method. The multisite solid catalyst efficiently promoted the asymmetric multicomponent reaction of aldehydes, malonates and nitromethane.
引用
收藏
页码：2006 / 2012
页数：7
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