Electrophilic 1,2-addition of oxoammonium salts to olefins

被引：0
|
作者：
Takata, T
Tsujino, Y
Nakanishi, S
Nakamura, K
Yoshida, E
Endo, T
机构：
[1] Tokyo Inst Technol, Res Lab Resources Utilizat, Midori Ku, Yokohama, Kanagawa 2268503, Japan
[2] Univ Osaka Prefecture, Grad Sch Engn, Dept Appl Chem, Sakai, Osaka 5998531, Japan
来源：
CHEMISTRY LETTERS | 1999年 / 09期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new reaction of oxoammonium salt is demonstrated. Addition of oxoammonium salts (1) to electron-rich olefins (2) such as vinyl ethers and enamines rapidly proceeded to give corresponding I,2-adducts (3) in high yields. The adducts 3 formed were further transformed by treatment with sodium ethoxide to isolable substitution products (4) in one pot reaction.
引用
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页码：937 / 938
页数：2
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